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王小林
  • 职称: 副教授
  • 岗位: 仅研究系列选择
  • 联系电话: 025-89680867
  • 办公地址: 南京大学地球科学与工程学院
  • 电子邮件: xlinwang@nju.edu.cn
  • 课题组链接:

个人简介

教育经历

工作经历

学术兼职

研究方向

(1) 实验地球化学采用可视化、在线分析方法,研究地壳—上地幔(21 - 1000 C,0.1 - 3 GPa)流体—熔体的热力学性质,进而为成岩、成矿研究提供基础实验制约; 采用先进的熔融毛细硅管合成包裹体技术,建立地质流体(盐度、S、B以及C-H-O-S-N体系挥发份)原位拉曼光谱定量分析方法,并对典型成岩、成矿体系进行解剖,以重建流体作用的古温度、压力场,进而恢复地质作用过程
(2) 石油地质学。采用流体包裹体分析、埋藏史恢复和同位素定年技术,厘定油气生成、运移和聚集的时限; 深埋条件下烃类热化学损耗的机理和动力学; 油气储层的成因及保存条件,侧重酸性流体作用下的次生溶蚀型储层发育机制

(3) 成矿作用机制。元素在熔体和流体间的分配规律; 热液流体中元素的迁移和沉淀机制,当前侧重W-Sn矿床


开授课程

 (1) 本科大三专业选修课《油气资源概论》(《能源地质学》),主讲

 (2) 矿床学研究生必须课程《流体作用与成矿》,与胡文瑄教授等合授

 (3) 大二暑期课程《区域地质测量》(安徽巢湖野外教学),主讲


科研项目

1、纵向课题

  (1) 国家自然科学基金委优秀青年基金项目: 热液流体实验地球化学 (Grant no. 41922023), 2020 - 2022, 120万, 主持

  (2) 国家自然科学基金委面上基金项目: 硫酸盐—水体系高温液—液不混溶作用的发生条件、机理及成矿意义 (Grant no. 41573054), 2016-2019, 主持

  (3) 国家自然科学基金委青年基金项目: 流体中镁离子性状与行为及其对白云石形成的制约(Grant no. 41203045), 2013-2015, 主持

  (4) 国家自然科学基金委重点基金项目: 含油气盆地溶蚀流体类型判识标志、水-岩作用机理及溶蚀型储层成因模式 (Grant no. 41830425), 2019 - 2023, 302万, 研究骨干

  (5) 国家自然科学基金委重点基金项目: 含油气盆地深部流体与围岩介质相互作用的物理化学过程和机理(Grant no. 41230312), 2013-2017, 研究骨干

   (6) 重点研发计划子课题: 高温高压条件下烃类相态转化及微观封闭机理 (Grant no. 2017YFC0603105), 2018 - 2021, 200万, 研究骨干

   (7) 国家科技重大专项子课题: 深层白云岩储层形成机理与发育模式(Grant no. 2011ZX05005-002-008HZ), 2011-2015, 研究骨干

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2、横向协作

     (1) 中石化研究院无锡石油地质研究所协作项目: 高压油气包裹体测温测压实验技术研究, 2018.09 - 2019.08, 主持

     (2) 中石化研究院协作项目: 特高含水条件下CO2与岩石相互作用规律研究(Grant no. GSYKY-B09-33), 2014-2015, 主持

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3、其他项目

(1) 中央高校基本科研业务费原创与交叉研究培育基金项目: 硫酸盐热还原反应的机理、动力学特征及其成矿意义, 2017-2018, 主持

学术成果

近年来,主要围绕热液流体,特别是含硫热液的地球化学行为开展基础性研究,获得了较为系统的、具有一定创新性的认识,为解决一些硫化物矿床和油气储层成因提供了新的理论依据,属于实验地球化学-金属成矿-油气成藏的交叉研究,同时也推动了可视化、原位观测实验技术的不断成熟。已以第一(含通讯)作者发表SCI论文19篇,累计发表论文50余篇。

代表性成果主要有:(1)建立了流体包裹体中常见组分的原位拉曼光谱定量分析方法,完善了可视化、原位观测实验技术(Geochimica et Cosmochimica Acta, 2011; Journal of Geochemical Exploration, 2013; Chemical Geology, 2020a; Petroleum Science, 2020);(2)发现了含MgSO4热液流体的液—液不混溶现象,并分析了其内在机制(Geochimica et Cosmochimica Acta, 2013);(3)揭示了海底热液和密西西比河谷型(MVT)铅锌矿成矿系统中金属元素(Zn, CdLi)和硫的迁移形式和富集规律,为成矿机制提供了新制约(Geochimica et Cosmochimica Acta, 2016, 2017Chemical Geology, 2017);(4)澄清了SO42-抑制白云石沉淀的争论,深化了白云岩成因动力学认识(Chemical Geology, 2016)。

研究成果获得教育部科技进步奖二等奖1项,于2019年获得国家自然科学基金委优秀青年基金项目资助。担任多家学术期刊审稿人,包括领域主流学术期刊Geochimica et Cosmochimica Acta、Chemical Geology、American Mineralogist, 以及Organic GeochemistryApplied Clay ScienceEnergy & FuelJournal of Chemical & Engineering DataApplied SpectroscopyJournal of Physical ChemistrySpectrochimica ActaPetroleum Science, Energy Exploration & Exploitation等,还有国内重要学术期刊如中国科学(Science China: Earth Sciences)、地质学报(Acta Geologica Sinica)、地质论评等。


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附部分成果

   (A) SCI检索论文

[32] Wang X.*, Qiu Y., Chou I-M., Zhang R., Li G., Zhong R. (2020) Effects of pH and salinity on the hydrothermal transport of tungsten: Insights from in situ Raman spectroscopic characterization of K2WO4-NaCl-HCl-CO2 solutions at temperatures up to 400 C. Geofluids, article ID 2978984, p1-12

[31] Qiu Y., Yang Y., Wang X.*, Wan Y., Hu W., Lu J., Tao G., Li Z., Meng F. (2020) In situ Raman spectroscopic quantification of aqueous sulfate: Experimetal calibration and application to natural fluid inclusions. Chemical Geology, 533: article no. 119447.

[30] Wang X.*, Qiu Y., Lu J., Chou I-M., Zhang W., Li G., Hu W., Li Z., Zhong R.* (2020) In situ Raman spectroscopic investigation of the hydrothermal speciation of tungsten: Implications for the ore-forming process. Chemical Geology, 532: article no. 119299.

[29] Wang L., Hu W.*, Wang X.*, Cao J., Yao S. (2020)  Halogens (Cl, Br, I) geochemistry in Middle Triassic carbonates: Implications for salinity and diagenetic alteration of I/(Ca + Mg) ratios. Chemical Geology, 533: article no. 119444.

[28] Qiu Y., Wang X.-L.*, Liu X., Cao J., Liu Y.-F., Xi B.-B., Gao W.-L. (2020) In situ Raman spectroscopic quantification of CH4-CO2 mixture: application to fluid inclusions hosted in quartz veins from the Longmaxi shales in Sichuan Basin, southwestern China. Petroleum Science, 17: 23 - 25 (Cover article).

[27] Chang C.*, Hu W., Wang X., Huang K.-J., Yang A., Zhang X. (2019) Nitrogen isotope evidence for an oligotrophic shallow ocean during the Cambrian Stage 4. Geochim. Cosmochim. Acta, 257: 49 - 67.

[26] Yang S., Hu W.*, Wang X., Jiang B., Yao S., Sun F., Huang Z., Zhu F. (2019) Duration, evolution, and implications of volcanic activity across the Ordovician-Silurian transition in the Lower Yangtze region, South China.Earth Planet. Sci. Lett., 518: 13 - 25.

[25] Hu W.-X., Kang X., Cao J., Wang X.-L., Fu B., Wu H.-G. (2018) Thermochemical oxidation of methane induced by high-valence metal oxides in a sedimentary basin. Nature Commumications2018(9): 5131.  

[24] Hu W.*, Wang X., Zhu D., You D., Wu H. (2018) An overview of types and characterization of hot fluids associated with reservoir formation in petroliferous basins. Energy Exploration & Exploitation, 36: 1359 – 1375.

[23] Chang C., Hu W., Fu Q., Cao J., Wang X., Wan Y., Yao S. (2018) Characteristics and formation processes of (Ba, K, NH4)-feldspar and cymrite from a lower Cambrian black shale sequence in Anhui Province, South China. Mineralogical MagazineDOI: https://doi.org/10.1180/minmag.2017.081.017.

[22] Wang X.*, Song Y., Chou I-M.*, Qiu Y. (2018) Raman spectroscopic characterization of cracking and hydrolysis of n-pentane and n-octadecane at 300 - 375 C with geological implications.Energy Exploration & Exploitation, doi: 10.1177/0144598717748762.

[21] Chang C., Hu W., Wang X., Yu H., Yang A., Cao J., Yao S. (2017) Carbon isotope stratigraphy of the lower to middle Cambrian on the eastern Yangtze Platform, South ChinaPalaeogeography, Palaeoclimatology, Palaeoecology 479, 90-101

[20] Wu H., Hu W., Tang Y., Cao J.,Wang X., Wang Y., Kang X. (2017) The impact of organic fluids on the carbon isotopic compositions of carbonate-rich reservoirs: case study of the Lucaogou Formation in the Jimusaer Sag, Junggar Basin, NW China. Marine and Petroleum Geology85, 136-150.

[19] Wan Y.,Wang X.*, Chou I-M., Hu W., Zhang Y., and Wang X. (2017) An Experimental Study of the Formation of Talc through CaMg(CO3)2–SiO2–H2O Interaction at 100–200°C and Vapor-Saturation Pressures. Geofluids, 3942826, 1-14. doi:10.1155/2017/3942826.

[18] Wan Y., Wang X.*, Hu W., Chou I-M., Wang X., Chen Y., Xu Z. (2017) In situ optical and Raman spectroscopic observations of the effects of pressure and fluid composition on liquid–liquid phase separation in aqueous cadmium sulfate solutions (400 C, 50 MPa) with geological and geochemical implications. Geochimica et Cosmochimica Acta 211, 133-152.

[17] Wang X.*, Wang X., Chou I-M., Hu W., Wan Y., and Li Z. (2017) Properties of lithium under hydrothermal conditions revealed by in situ Raman spectroscopic characerization of Li2O-SO3-H2O(D2O) systmes at temperatures up to 420 C. Chemical Geology 451, 104-115.

 [16] Wang X., Wang X.*, Hu W., Wan Y., Cao J., Lv C., Wang R., Cui M. (2017) Supercritical CO2-involved water-rock interactions at 85 C and partial pressures of 10-20 MPa: Sequestration and enhanced oil recovery. Energy Exploration & Exploitation, 35(2): 237-258.

[15] WangX.*, Wan Y., Hu W., Chou I-M., Cao J., Wang X., Wang M. and Li Z. (2016) In situ observations of liquid–liquid phase separation in aqueous ZnSO4 solutions at temperatures up to 400° C: Implications for Zn2+–SO42 association and evolution of submarine hydrothermal fluids. Geochimica et Cosmochimica Acta 181, 126-143.

[14] WangX.*, Chou I.M., Hu W., Yuan S., Liu H., Wan Y. and Wang X. (2016) Kinetic inhibition of dolomite precipitation: Insights from Raman spectroscopy of Mg2+–SO42 ion pairing in MgSO4/MgCl2/NaCl solutions at temperatures of 25 to 200° C. Chemical Geology 435, 10-21.

[13] WangX.*, Wan Y., Hu W., Chou I-M., Cai S., Lin N., Zhu Q. and Li Z., (2016) Visual and in situ Raman spectroscopic observations of the liquid–liquid immiscibility in aqueous uranyl sulfate solutions at temperatures up to 420° C. The Journal of Supercritical Fluids 112, 95-102.

[12] Wu H., Hu W., Cao J., Wang X., Wang X., Liao Z. (2016) A unique lacustrine mixed dolomitic-clastic sequence for tight oil reservoir within the middle Permian Lucaogou Formation of the Junggar Basin, NW China: Reservoir characteristics and origin. Marine and Petroleum Geology 76, 115-132.

[11] Chang C., Hu W., Fu Q., Cao J., Wang X. and Yao S. (2016) Characterization of trace elements and carbon isotopes across the Ediacaran-Cambrian boundary in Anhui Province, South China: Implications for stratigraphy and paleoenvironment reconstruction. Journal of Asian Earth Sciences 125, 58-70.

[10] Liao Z., Hu W., Cao J., Wang X., Yao S. and Wan Y. (2016) Permian–Triassic boundary (PTB) in the Lower Yangtze Region, southeastern China: A new discovery of deep-water archive based on organic carbon isotopic and U–Pb geochronological studies.Palaeogeography, Palaeoclimatology, Palaeoecology 451, 124-139.

[9] Liao Z., Hu W., Cao J., Wang X., Yao S., Wu H. and Wan Y. (2016) Heterogeneous volcanism across the Permian–Triassic Boundary in South China and implications for the Latest Permian Mass Extinction: New evidence from volcanic ash layers in the Lower Yangtze Region. Journal of Asian Earth Sciences 127, 197-210

[8] Wan Y., WangX.*, Hu W. and Chou I-M. (2015) Raman Spectroscopic Observations of the Ion Association between Mg2+ and SO42– in MgSO4-Saturated Droplets at Temperatures of ≤ 380° C. The Journal of Physical Chemistry A 119, 9027-9036.

[7] Wang L., Hu W.*, Wang X., Cao J., Chen Q., Seawater normalized REE patterns of dolomite in Geshan and Panlongdong sections, China: Implications for tracing dolomitization and diagenetic fluids, Marine and Petroleum Geology, 2014, 56: 63-73

[6] Yuan S., Chou I.-M., Burruss R.C.,Wang X., and Li J. (2013) Disproportionation and thermochemical sulfate reduction reactions in S-H2O-CH4 and S-D2O-CH4 systems from 200 to 300 C. Geochimica et Cosmochimica Acta118, 263-275. 

[5] Wang X.*, Hu W., and Chou I.-M. (2013) Raman spectroscopic characterization on the OH stretching bands in NaCl-Na2CO3-Na2SO4-CO2-H2O systems: Implications for the measurement of chloride concentrations in fluid inclusions. Journal of Geochemical Exploration132, 111-119.

[4] Wang X.* Chou I.-M., Hu W., and Burruss R.C. (2013) In-situ observations of liquid-liquid phase separation in aqueous MgSO4 solutions. Geochimica et Cosmochimica Acta103, 1-10.

[3] Wang X.* Chou I.-M., Hu W., Burruss R.C., Sun Q. and Song Y. (2011) Raman spectroscopic measurements of CO2 density: Experimental calibration with high-pressure optical cell (HPOC) and fused silica capillary capsule (FSCC) with application to fluid inclusion observations. Geochimica et Cosmochimica Acta75, 4080-4093.

[2] Wang X.,  Hu W., Yao S., Chen Q. and Xie X. (2011) Carbon and strontium isotopes and global correlation of Cambrian Series 2-Series 3 carbonate rocks in the Keping area of the northwestern Tarim Basin, NW China. Marine and Petroleum Geology28, 992-1002.

[1] Wang X.,Jin Z., Hu W., Zhang J., Qian Y., Zhu J. and Li Q. (2009) Using in situ REE analysis to study the origin and diagenesis of dolomite of Lower Paleozoic, Tarim Basin. Science in China Series D-Earth Sciences 52, 681-693.

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(B) 中文核心期刊论文

[23] 高婉露, 王小林*, 丘靥, 席斌斌, 杨源显, 郑建帆, 曾世豪, 张婧玥, 李真. C-H-O-N体系挥发分的拉曼定量分析: 压力、温度和流体组成的影响. 地球化学, 2020, 49(2): 121-140

[22] 刘显, 陈强路, 王小林*,丘靥, 杨源显. 方解石晶体定向性对水的拉曼光谱影响的实验评估—天然包裹体盐度的测定. 南京大学学报(自然科学版), 2020, 56(3): 297-307

[21] 杨源显, 王小林*, 席斌斌, 丘靥, 高婉露, 万野, 李真. 应用拉曼光谱定量分析流体中硫酸盐质量摩尔浓度: 内标选择和流体组分对分析结果的影响. 地球化学, 2019, 48(4): 403 - 419.

[20] 王小林*, 万野, 胡文瑄, 尤东华, 曹剑, 朱东亚, 李真 . 白云石与富硅流体的水—岩反应实验及其储层地质意义. 地质论评, 2017, 63(6): 1639-1652.

[19] 王晓宇, 王小林*, 万野, 胡文瑄. 一种新的热台温度校准方法: 硫酸盐—水体系液—液相分离原位观测. 地球化学, 2017, 46(4), 319-332.

[18] 王小林*, 胡文瑄张军涛朱井泉万野.塔里木盆地和田1井中寒武统膏岩层段发现原生白云石地质论评, 2016, 62(2) : 419-433

[17] 廖志伟胡文瑄王小林曹剑姚素平和万野下扬子PTB界线深水相区粘土岩的火山成因研究及对LPME的指示意义地质学报90(4), 785-800. 

[16] 胡文瑄*,朱井泉,王小林,由雪莲,何凯,塔里木盆地柯坪地区寒武系微生物白云岩特征、成因及意义,石油与天然气地质,201435(6): 860-869

[15] 王利超,胡文瑄*王小林,下扬子宜兴葛山三叠系周冲村组白云岩化过程及元素地球化学响应,地球化学,201443(3): 255-266

[14] 张军涛*,胡文瑄,王小林,塔里木盆地寒武系鞍状白云石孔隙充填物差异与成因,沉积学报,201332(2): 253-259

[13] 王小林,胡文瑄,李庆,朱井泉. (2011) 塔里木盆地蓬莱坝剖面寒武系第二统-第三统界线处碳同位素负异常及其地质意义.地质论评 57(1)16-23.

[12] 张军涛,胡文瑄,王小林,钱一雄,吴世祥. (2011) 塔里木盆地西北缘寒武系中热水白云石团块特征及其成因研究. 地质学报85, 234-245.

[11] 王小林,胡文瑄,陈琪,李庆,朱井泉,张军涛. (2010) 塔里木盆地柯坪地区上震旦统藻白云岩特征及其成因机理.地质学报 841479-1494.

[10] 李庆,胡文瑄,张军涛,王小林,朱井泉. (2010) 塔里木盆地西北缘中寒武统硅质岩特征与形成环境. 矿物学报 30, 293-303.

[9] 胡文瑄,陈琪,王小林,曹剑. (2010) 白云岩储层形成演化过程中不同流体作用的稀土元素判别模式. 石油与天然气地质31, 810-818. 

[8] 王小林,胡文瑄,钱一雄,张军涛,谢小敏,李庆. (2009) 塔里木盆地柯坪地区中寒武统藻白云岩去白云岩化研究.矿物学报 2956-62.

[7] 谢小敏,胡文瑄,王小林,钱一雄,张军涛,曹剑,李庆. (2009) 新疆柯坪地区寒武纪-奥陶纪碳酸盐岩沉积旋回的碳氧同位素研究.地球化学38, 75-88. 

[6] 吴仕强,朱井泉,胡文瑄,张军涛,王小林,苏永斌. (2009) 塔里木盆地寒武系-奥陶系白云岩稀土元素特征及其成因意义. 现代地质23, 638-647.

[5] 王小林,胡文瑄,张军涛,钱一雄,朱井泉,吴仕强. (2008) 白云岩物质组分与结构对微孔储集体系形成的制约-以塔里木盆地下古生界白云岩为例。天然气地球科学 19(3)320-326.

[4] 张军涛,胡文瑄,钱一雄,王小林,谢小敏. (2008) 塔里木盆地白云岩储层类型划分、测井模型及其应用.地质学报82, 380-386. 

[3] 张学丰,胡文瑄,张军涛,王小林,谢小敏. (2008) 塔里木盆地下奥陶统白云岩化流体来源的地球化学分析.地学前缘15, 80-89. 

[2] 吴仕强,朱井泉,王国学,胡文瑄,张军涛,王小林. (2008) 塔里木盆地寒武-奥陶系白云岩结构构造类型及其形成机理. 岩石学报24, 1390-1400. 

[1] 张军涛,胡文瑄,钱一雄,王小林,朱井泉,张洪安,苏娟,吴仕强. (2008) 塔里木盆地中央隆起区上寒武统-下奥陶统白云岩储层中两类白云石充填物:特征与成因. 沉积学报26, 957-966.

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(C) 专利申请与授权

[2]王小林, 胡文瑄, 曹剑. 一种可视化样品腔、包裹体测温系统及方法, 国家发明专利, 申请号: 202010396562.8 [2020年]

[1]王小林, 王晓宇, 万野. 一种热台温度校准方法, 国家发明专利,专利号: 201611020222.5 [2016年]

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    (D) 学术会议论文

[16] Wang X (2017) In situ Raman spectroscopic observation of water-hydrocarbon-mineral interactions. Invited talk in International Forum in Organic-Inorganic Interaction During Hydrocarbon Accumulation, Beijing.

[15] 王小林 (2017) 液—液不混溶与元素迁移、富集. 口头报告, 固体地球科学重点实验室联盟2017年度联合学术委员会, 北京.

[14] 王小林 (2017) 富硅流体与白云石的水—岩反应实验及其储层地质意义. 口头报告, 第六届全国沉积学大会, 南京.

[13] 王小林, 胡文瑄, 万野, 王晓宇 (2016) 热液流体液—液不混溶及其地质意义. 口头报告, 第十八届全国包裹体及流体学术研讨会, 成都.

[12] 王小林 (2014) 硫酸盐—水体系高温相行为原位观测及意义. Invited talk. 三亚.

[11] 王小林, 胡文瑄, I-Ming Chou (2013) MgSO4-H2O体系高温相行为及离子络合作用原位观测与地质意义. 口头报告, 第七届世界华人地质科学研讨会, 成都.

[10] 王小林 (2012) 流体中Mg2+与SO42-的络合形式及其对白云石成因的启示. 口头报告, 第十七届包裹体及地质流体学术研讨会, 杭州.

[9] 王小林, 胡文瑄, 王利超, 张军涛 (2011)塔里木盆地震旦系—寒武系白云岩微生物成因及意义. 口头报告, 白云岩成因及油气储集层研讨会, 北京.

[8] Wang X., Chou I-M., Wan Y. (2017) Effect of pressure on liquid-liquid phase separation of aqueous sulfate solution observed in fused silica capillary tubes at elevated temperatures. Goldschmidt 2017, 2017001495.

[7] Wang X., Hu W., Xie X. (2010) Carbon, oxygen and strontium isotopic compositions of Lower to Middle Cambrian carbonates in the northwestern Tarim Basin, China. Geochimica et Cosmochimica Acta 74, A1108. 

[6] Hu W., Wang X., Li Q. (2010) The primary dolomite of microbial origin in the Late Neoproterozoic algal dolomite, Tarim Basin, China. Geochimica et Cosmochimica Acta 74, A426. 

[5] Zhang J., Hu W., Qian Y., Wang X., Zhu J. (2008) Petrography, geochemistry and origin of cement dolomite in the Lower Paleozoic dolomite of the Central uplift, Tarim Basin. Geochimica et Cosmochimica Acta 72, A15. 

[4] Wang X.L., Hu W.X., Zhang W.L., Zhang J.T. (2007) The composition and texture constraints on micro-porosities of dolomite reservoirs, Tarim Basin, NW China. Geochimica et Cosmochimica Acta71, A1087. 

[3] Hu W., Xie X., Zhang J., Wang X. (2007) Oxygen and Carbon isotope composition and implication of Early Palaeozoic dolomites in Keping, Tarim Basin. Geochimica et Cosmochimica Acta71, A421. 

[2] Zhang J., Hu W., Qian Y., Wang X., Cao J., Zhu J., Li Q., Xie X. (2009) Formation of saddle dolomites in Upper Cambrian carbonates, western Tarim Basin (northwest China): Implications for fault-related fluid flow. Marine and Petroleum Geology26, 1428-1440.

[1] Zhang X., Hu W., Jin Z., Zhang J., Qian Y., Zhu J., Zhu D., Wang X., Xie X. (2008) REE compositions of Lower Ordovician dolomites in Central and North Tarim Basin, NW China: A potential REE proxy for ancient seawater. Acta Geologica Sinica82, 610-621.

荣誉奖励

     (1) 国家自然科学基金委优秀青年基金人才项目(2019)

     (2) 全国大学生地质技能竞赛优秀辅导教师(2016)

     (3) 教育部科技进步二等奖(4/6, 2015)

     (4) 南京大学中国银行青年教师教学成果二等奖(2015)

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